RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of temperature of reactants on rate of reaction.

By the end of the lesson, the learner should be able to:
Explain the effect of temperature on rate of reaction.

Group experiments: investigate the effects of temperature on the rate of reaction of sodium thiosulphate with dilute HCl.
Sketch and interpret relevant graphs.
Discuss the collision theory and effects of activation energy.

Sodium thiosulphate heated at different temperatures, dilute HCl, stopwatches.
Graph papers.

K.L.B. BK IV
Pages 80-83

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of change in surface area of reactants on the rate of a reaction.
Effect of a suitable catalyst on the rate of a reaction

By the end of the lesson, the learner should be able to:
Explain the effect of change in surface area on the rate of a reaction.

Group experiment/ teacher demonstration.

Compare reactions of marble chips with dilute HCl and that of marble chips powder with equally diluted HCl.

Collect evolved gas in each case.

Teacher asks probing questions related to the observations made.

Marble chips, marble chips powder, syringes, conical flasks with stoppers, 1M HCl.
Hydrogen peroxide, manganese (IV) oxide.

K.L.B. BK IV
Pages 83-85

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of light on rate of specific reactions.

By the end of the lesson, the learner should be able to:
Identify reactions that are affected by light.

Teacher demonstration: decomposition of silver bromide in the presence of light.
Mention other examples of reactions affected by light.

Silver bromide.

K.L.B. BK IV
Pages 89-91

RATES OF REACTION & REVERSIBLE REACTIONS.

Reversible reactions.
State of equilibrium in chemical reactions.
Le Chatelier?s Principle.

By the end of the lesson, the learner should be able to:
Write down equations for reversible reactions.
Define the term equilibrium as used in reversible reactions.
Write down equations of reversible reactions in a state of equilibrium.

Q/A: review temporary and permanent changes.
Teacher demonstration: heating crystals of hydrated copper (II) sulphate, then ?hydrating? them.
Write the corresponding chemical equations.
Give further examples of reversible reactions.


Brief discussion, giving examples of chemical equations for reversible reactions.

Crystals of hydrated copper (II) sulphate.
student book
Add 2M sodium hydroxide,

K.L.B. BK IV
Pages 91-93
K.L.B. BK IV
Pages 94-95

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of change of pressure and temperature on equilibrium shift.

By the end of the lesson, the learner should be able to:
Explain the effect of change of pressure & te,perature on equilibrium shift.

Q/A: review kinetic theory of matter.
Q/A & discussion on effect of change of pressure / temperature on shifting of equilibrium; giving specific examples of chemical equations.
Written assignment.

student book

K.L.B. BK IV
Pages 97-101

RATES OF REACTION & REVERSIBLE REACTIONS.

The Haber Process.

By the end of the lesson, the learner should be able to:
Explain the concept optimum conditions of a chemical equilibrium.
Explain factors that change the position of equilibrium of the Harber process.

Q/A and detailed discussion on change of pressure, temperature, concentration of ammonia and effect of presence of a suitable catalyst on the Haber process.

student book

K.L.B. BK IV
Pages 102-103

RATES OF REACTION & REVERSIBLE REACTIONS.
RADIOACTIVITY

The Contact Process.
Definition of radioactivity.

By the end of the lesson, the learner should be able to:
Explain how change of temperature and pressure affect rate of manufacture of sulphur (VI) acid.

Probing questions and brief discussion.

Assignment.

student book

K.L.B. BK IV
Pages 103-104

RADIOACTIVITY

Alpha particles.
Equations involving alpha particles.
Beta particles. Gamma rays.
Radioactive Half-Life.

By the end of the lesson, the learner should be able to:
State properties of alpha particles.
Describe methods of detecting alpha particles.

Write down and balance equations involving alpha particles.

Q/A: position of helium in the periodic table.

Expository approach:


Q/A: Review atomic and mass numbers.
Examples of balanced equations.
Supervised practice.

student book
student book
Dice.

K.L.B. BK IV
Pages 251-253
K.L.B. BK IV
Page 257

RADIOACTIVITY

Radioactive decay curve.
Nuclear fusion and nuclear fission. Applications of radioactivity.

By the end of the lesson, the learner should be able to:
Plot a radioactive decay curve to deduce the
half ?life from the curve.

Drawing a radioactive decay curve inferring the half-life of the sample from the graph.

Graph papers.
student book

K.L.B. BK IV
Pages 254-5

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Endothermic and Exothermic Reactions.

By the end of the lesson, the learner should be able to:






To differentiate between endothermic & exothermic reactions.

Investigate temperature changes in solution formation.

Obtain changes in temperature when ammonium nitrate and sodium hydroxide are dissolved in water, one at a time.

Ammonium nitrate,
Sodium hydroxide, thermometers.

K.L.B. BK IV
Pages 32-33

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Energy level diagrams.

By the end of the lesson, the learner should be able to:
Represent endothermic reactions with exothermic reactions with energy level diagrams.

Probing questions on relative energies of reactants and products in endothermic and exothermic and endothermic reactions.

student book

K.L.B. BK IV
Pages 33-35

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Enthalpy Notation. Change of state.
CAT

By the end of the lesson, the learner should be able to:
Define the term enthalpy.
Distinguish positive enthalpy change from negative enthalpy change.

Determine the M.P/ B.P of a pure substance.

Q/A and brief discussion.
Class experiments: determine B.P of pure water/ M.P of naphthalene / ice.
Use experimental results to plot temperature-time graphs.
Explain the shape of the graphs.
Q/A: review kinetic theory of matter.
Apply the theory to explain the shape of the graph, and nature of bonding in substances.

Ice, naphthalene, thermometers, graph papers.

K.L.B. BK IV
Pages 35-39

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution.

By the end of the lesson, the learner should be able to:
Determine molar heat of solution of given substances.

Dissolve known masses of ammonia nitrate / sodium hydroxide in known volumes of water.
Determine temperature changes.
Calculate molar heat of solution. Supervised practice.

Ammonia nitrate / sodium hydroxide, thermometers.

K.L.B. BK IV
Pages 40-41

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of H2SO4.

By the end of the lesson, the learner should be able to:
Determine molar heat of solution of H2SO4.

Dissolve some known volume of conc. H2SO4 in a given volume of water.
Note the change in temperature.
Work out the molar heat of solution of H2SO4.

Conc. H2SO4, thermometers.

K.L.B. BK IV
Pages 42-45

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Enthalpy of combustion. Enthalpy of combustion.

By the end of the lesson, the learner should be able to:
Define the term enthalpy of combustion.
Determine the enthalpy of combustion of ethanol.
Explain why actual heats of combustion are usually lower than the theoretical values.

Group experiments / teacher demonstration.

Obtain and record results.


Work out calculations.

Ethanol, distilled water, thermometer, clear wick, tripod stand and wire gauze.

K.L.B. BK IV
Pages 45-48

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of displacement of ions.

By the end of the lesson, the learner should be able to:
Define the term molar heat of solution of displacement of ions.
Determine the molar heat of solution of displacement of ions.

Group experiments/ teacher demonstration.
Note steady temperature of solutions formed when zinc/ iron / magnesium reacts with copper sulphate solution.
Work out the molar heat of displacement of a substance from a solution of its ions.

Zinc, iron, magnesium, copper sulphate solution.

K.L.B. BK IV
Pages 48-50

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of neutralization.

By the end of the lesson, the learner should be able to:
Define the term neutralization.
Determine the molar heat of neutralization of HCl with NaOH.

Class experiments:
Neutralize 2M HCl of known volume with a determined volume of 1M / 2M sodium hydroxide.
Note highest temperature of the solution.
Work out the molar heat of neutralization.
Solve other related problems.
Assignment.

2M HCl of known volume, 1M / 2M sodium hydroxide.

K.L.B. BK IV
Pages 50-53

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Standard enthalpy changes.
Hess?s Law.

By the end of the lesson, the learner should be able to:
Define the term standard enthalpy change.
Denote standard enthalpy change with the correct notation.

State Hess?s law.

Solve problems related to Hess?s law.

Exposition & brief discussion.
Detailed discussion & guided discovery of the law.
Illustrations of energy cycles and energy levels leading to Hess?s law.
Worked examples.
Supervised practice
Written assignment.

student book

K.L.B. BK IV
Pages 54-56
K.L.B. BK IV
Pages 56-57

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Heat of solution hydration energy and lattice energy.

By the end of the lesson, the learner should be able to:
Define the terms lattice energy and hydration energy.
Explain the relationship between heat of solution, hydration energy.
Solve related problems.

Exposition of new concepts.
Guided discovery of the relationship between heat solution hydration energy and lattice energy.
Worked examples.
Assignment.

student book

K.L.B. BK IV
Pages 60-64

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Heat values of fuels.

By the end of the lesson, the learner should be able to:
Define the term fuel.
Describe energy changes when a fuel undergoes combustion.
Outline factors considered when choosing a suitable fuel.

Probing questions and brief discussion.

student book

K.L.B. BK IV
Pages 64-66

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Environmental effects of fuels.

By the end of the lesson, the learner should be able to:
Outline some environmental effects of fuels.
Identify measures taken to reduce environmental
pollution.

Q/A & open discussion.

student book

K.L.B. BK IV
Pages 67-68

ACIDS, BASES AND SALTS.

Strength of acids. Acids in aqueous form.
pH values of acids. Electrical conductivities of aqueous acids.

By the end of the lesson, the learner should be able to:


Define an acid in terms of hydrogen ions.

Explain strength of acids in aqueous form in terms of number of hydrogen ions present.
Determine strength of acids using pH values.

Determine strengths of acids by comparing their electrical conductivities.

Classify acids as either strong or weak in terms of partial dissociations in aqueous solutions.

Class experiments: investigate reactions of magnesium and zinc carbonate with different acids.
Make and record observations in tabular form.
Make deductions from the observations.
Write relevant chemical equations and ionic equations.
Detailed discussion leading to the definition of an acid and explanation of strength of an acid.

Q/A: review determination of strength of acids using a litmus paper and pH scale.
Class / group experiments: record colour of universal indicator in
2M HCl and 2M ethanoic acid.
Set up voltameters of 2M HCl and 2M ethanoic acid in turns.
Record amounts of current .
Discuss the observations.
Write corresponding ionic equations.

Magnesium strip, zinc carbonate,
2M HCl,
2M H2SO4,
2M ethanoic acid.
Universal
indicator,
2M HCl,
2M ethanoic acid,
dry cells,
carbon electrodes,
milli-ammeters,
wires, switches etc.

K.L.B. BK IV
Pages 1-4
K.L.B. BK IV
Pages 4-6

ACIDS, BASES AND SALTS.

Definition of a base in terms of hydroxide ions.

By the end of the lesson, the learner should be able to:
Define a base in terms of hydroxide ions.

Teacher demonstration:
Dissolve calcium hydroxide in water.
Carry out litmus test on the resulting solution.
Discuss the results; hence define a base in terms of hydroxide ions.

Red litmus paper, calcium hydroxide solid.

K.L.B. BK IV
Pages 6-7

ACIDS, BASES AND SALTS.

Neutralization reaction.

By the end of the lesson, the learner should be able to:
Determine the results of reaction of an acid and a base.

Add 1M HCl to an aqueous solution of Calcium hydroxide drop wise until colour, change of the universal indicator is noted.
Write ionic equation for the reaction.

1M HCl,
Calcium hydroxide,
universal indicator.

K.L.B. BK IV
Page 7

ACIDS, BASES AND SALTS.

Strength of bases.

By the end of the lesson, the learner should be able to:
Compare strengths of bases using pH values and electrical conductivity.


Classify bases/ alkali as either strong or weak in terms of complete / partial ionization.

Carry out pH tests of 2M NaOH and 2M ammonia solution using universal indicator solutions; and observe colour changes.

Carry out electrical conductivity tests of voltameters of the above solutions.

Discussion: relate number of hydroxide ions to pH values and electrical conductivity of bases.

2M NaOH,
2M ammonia solution, universal indicator solutions, dry cells,
carbon electrodes,
milliammeters,
wires, switches etc

K.L.B. BK IV
Pages 7-9

ACIDS, BASES AND SALTS.

Dissolving hydrogen chloride gas in water / methylbenzene.
Dissolving ammonia gas in water/ methylbenzene.

By the end of the lesson, the learner should be able to:
Define a polar and a non-polar solvent.

Teacher demonstration:
Dissolving HCl gas in different solvents.
Discuss the observations.
Write down related balanced chemical equations.

Ammonia gas,
Methylbenzene, hydrogen chloride gas.
Methylbenzene.

K.L.B. BK IV
Pages 9-11

ACIDS, BASES AND SALTS.

Amphoteric oxides.

By the end of the lesson, the learner should be able to:
Define an amphoteric oxide.
Identify some amphoteric oxides.

Class experiment:
Carry out acid / base reactions with metal oxides.
Q/A: make deductions from the results.
Writing and balancing relevant equations.

2M Nitric acid
2M NaOH,
HNO3.
Amphoteric oxides.

K.L.B. BK IV
Pages 12-14

ACIDS, BASES AND SALTS.

Amphoteric oxides.
Precipitation Reactions.
Solubility of chlorides sulphites and sulphates.

By the end of the lesson, the learner should be able to:
Define an amphoteric oxide.
Identify some amphoteric oxides.

Define a precipitate.
Write ionic equations showing formation of precipitates.

Class experiment:
Carry out acid / base reactions with metal oxides.
Q/A: make deductions from the results.
Writing and balancing relevant equations.


Q/A: review definition of a salt.
Class experiment;
Add sodium carbonate or a suitable carbonate to various salt solutions containing Mg2+, Al3+, Ca2+, etc.
Make observations and discuss the results.

2M Nitric acid
2M NaOH,
HNO3.
Amphoteric oxides.
Soluble carbonates e.g. Na2CO3, K2CO3, (NH4)2CO3
Salt solutions containing Mg2+, Al3+, Ca2+, etc.
0.1M solution containing Pb2+, 2M NaCl solution, 2M sodium sulphate, source of heating.

K.L.B. BK IV
Pages 12-14
K.L.B. BK IV
Pages 14-16

ACIDS, BASES AND SALTS.

Equations for formation of insoluble chlorides, sulphites and sulphates.

By the end of the lesson, the learner should be able to:
Write down equations for formation of insoluble chlorides, sulphites and sulphates.

Q/A: review observations made in the above experiments.
Discuss the solubility of the cations.
Write relevant ionic equations.

student book

K.L.B. BK IV
Pages 17-18

ACIDS, BASES AND SALTS.

Complex ions.

By the end of the lesson, the learner should be able to:
Explain formation of complex ions.

Add drops of 2M sodium hydroxide / 2M ammonia solution to a solution containing Mg2+, Zn2+, etc.

Make observations and discuss the results.

2M Sodium hydroxide (2M ammonia solution),
solution containing Mg2+, Zn2+, etc.

K.L.B. BK IV
Pages 18-20

ACIDS, BASES AND SALTS.

Solubility of a salt at a given temperature.

By the end of the lesson, the learner should be able to:
Define the term solubility.
Determine solubility of a given salt at room temperature.

Q/A: review the terms saturated, unsaturated solutions & crystallization.
Class experiment: determine mass of a solute that dissolves in 100cc of water at room temperature.

Suitable solutes.

K.L.B. BK IV
Pages 20-21

ACIDS, BASES AND SALTS.

Problems solving on solubility.
Effect of temperature on solubility of a solute in a solvent.

By the end of the lesson, the learner should be able to:
Solve problems involving solubility of a solute in a solvent at a given temperature.
Investigate the effect of temperature on solubility of a solute in a solvent.

Worked examples.
Supervised practice.
Written assignment.
Experiments involving solubility of KClO3 at different temperatures.
Note temperatures at which crystallization occurs.
Oral questions and discussion.

Evaporating dish, watch glass, heating source, thermometer.

KClO3 thermometers, source of heat.

K.L.B. BK IV
Pages 21-22
K.L.B. BK IV
Pages 22-25

ACIDS, BASES AND SALTS.

Effects of various salts on soap.

By the end of the lesson, the learner should be able to:
Determine the effects of various salts on soap.

Group experiments: form soap lather in distilled water, tap water, rainwater, dilute solution of sodium chloride and solutions containing Ca2+ and Zn2+.
Note volume of soap that forms lather readily.

distilled water, tap water, rainwater, dilute solution of sodium chloride and solutions containing Ca2+ and Zn2+.

K.L.B. BK IV
Pages 25-27

ACIDS, BASES AND SALTS.

Removal of hardness of water.

By the end of the lesson, the learner should be able to:
Identify ions for hardness of water.
Identify methods of removing hardness of water.
State merits & demerits of hard water.

Review results of above experiments.

Probing questions & brief discussion.

Assignment.

student book

K.L.B. BK IV
Pages 27-29