ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Endothermic and Exothermic Reactions.
Energy level diagrams.

By the end of the lesson, the learner should be able to:






To differentiate between endothermic & exothermic reactions.

Represent endothermic reactions with exothermic reactions with energy level diagrams.

Investigate temperature changes in solution formation.

Obtain changes in temperature when ammonium nitrate and sodium hydroxide are dissolved in water, one at a time.

Probing questions on relative energies of reactants and products in endothermic and exothermic and endothermic reactions.

Ammonium nitrate,
Sodium hydroxide, thermometers.
student book

K.L.B. BK IV
Pages 32-33
K.L.B. BK IV
Pages 33-35

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Enthalpy Notation. Change of state.

By the end of the lesson, the learner should be able to:
Define the term enthalpy.
Distinguish positive enthalpy change from negative enthalpy change.

Determine the M.P/ B.P of a pure substance.

Q/A and brief discussion.
Class experiments: determine B.P of pure water/ M.P of naphthalene / ice.
Use experimental results to plot temperature-time graphs.
Explain the shape of the graphs.
Q/A: review kinetic theory of matter.
Apply the theory to explain the shape of the graph, and nature of bonding in substances.

Ice, naphthalene, thermometers, graph papers.

K.L.B. BK IV
Pages 35-39

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

CAT

By the end of the lesson, the learner should be able to:

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution.

By the end of the lesson, the learner should be able to:
Determine molar heat of solution of given substances.

Dissolve known masses of ammonia nitrate / sodium hydroxide in known volumes of water.
Determine temperature changes.
Calculate molar heat of solution. Supervised practice.

Ammonia nitrate / sodium hydroxide, thermometers.

K.L.B. BK IV
Pages 40-41

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of H2SO4.

By the end of the lesson, the learner should be able to:
Determine molar heat of solution of H2SO4.

Dissolve some known volume of conc. H2SO4 in a given volume of water.
Note the change in temperature.
Work out the molar heat of solution of H2SO4.

Conc. H2SO4, thermometers.

K.L.B. BK IV
Pages 42-45

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Enthalpy of combustion. Enthalpy of combustion.

By the end of the lesson, the learner should be able to:
Define the term enthalpy of combustion.
Determine the enthalpy of combustion of ethanol.
Explain why actual heats of combustion are usually lower than the theoretical values.

Group experiments / teacher demonstration.

Obtain and record results.


Work out calculations.

Ethanol, distilled water, thermometer, clear wick, tripod stand and wire gauze.

K.L.B. BK IV
Pages 45-48

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of displacement of ions.

By the end of the lesson, the learner should be able to:
Define the term molar heat of solution of displacement of ions.
Determine the molar heat of solution of displacement of ions.

Group experiments/ teacher demonstration.
Note steady temperature of solutions formed when zinc/ iron / magnesium reacts with copper sulphate solution.
Work out the molar heat of displacement of a substance from a solution of its ions.

Zinc, iron, magnesium, copper sulphate solution.

K.L.B. BK IV
Pages 48-50

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of displacement of ions.

By the end of the lesson, the learner should be able to:
Define the term molar heat of solution of displacement of ions.
Determine the molar heat of solution of displacement of ions.

Group experiments/ teacher demonstration.
Note steady temperature of solutions formed when zinc/ iron / magnesium reacts with copper sulphate solution.
Work out the molar heat of displacement of a substance from a solution of its ions.

Zinc, iron, magnesium, copper sulphate solution.

K.L.B. BK IV
Pages 48-50

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of neutralization.

By the end of the lesson, the learner should be able to:
Define the term neutralization.
Determine the molar heat of neutralization of HCl with NaOH.

Class experiments:
Neutralize 2M HCl of known volume with a determined volume of 1M / 2M sodium hydroxide.
Note highest temperature of the solution.
Work out the molar heat of neutralization.
Solve other related problems.
Assignment.

2M HCl of known volume, 1M / 2M sodium hydroxide.

K.L.B. BK IV
Pages 50-53

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of neutralization.
Standard enthalpy changes.

By the end of the lesson, the learner should be able to:
Define the term neutralization.
Determine the molar heat of neutralization of HCl with NaOH.
Define the term standard enthalpy change.
Denote standard enthalpy change with the correct notation.

Class experiments:
Neutralize 2M HCl of known volume with a determined volume of 1M / 2M sodium hydroxide.
Note highest temperature of the solution.
Work out the molar heat of neutralization.
Solve other related problems.
Assignment.

Exposition & brief discussion.

2M HCl of known volume, 1M / 2M sodium hydroxide.
student book

K.L.B. BK IV
Pages 50-53
K.L.B. BK IV
Pages 54-56

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Hess?s Law.

By the end of the lesson, the learner should be able to:
State Hess?s law.

Solve problems related to Hess?s law.

Detailed discussion & guided discovery of the law.
Illustrations of energy cycles and energy levels leading to Hess?s law.
Worked examples.
Supervised practice
Written assignment.

student book

K.L.B. BK IV
Pages 56-57

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Hess?s Law.

By the end of the lesson, the learner should be able to:
State Hess?s law.

Solve problems related to Hess?s law.

Detailed discussion & guided discovery of the law.
Illustrations of energy cycles and energy levels leading to Hess?s law.
Worked examples.
Supervised practice
Written assignment.

student book

K.L.B. BK IV
Pages 56-57

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Heat of solution hydration energy and lattice energy.

By the end of the lesson, the learner should be able to:
Define the terms lattice energy and hydration energy.
Explain the relationship between heat of solution, hydration energy.
Solve related problems.

Exposition of new concepts.
Guided discovery of the relationship between heat solution hydration energy and lattice energy.
Worked examples.
Assignment.

student book

K.L.B. BK IV
Pages 60-64

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Heat values of fuels.
Environmental effects of fuels.

By the end of the lesson, the learner should be able to:
Define the term fuel.
Describe energy changes when a fuel undergoes combustion.
Outline factors considered when choosing a suitable fuel.

Outline some environmental effects of fuels.
Identify measures taken to reduce environmental
pollution.

Probing questions and brief discussion.
Q/A & open discussion.

student book

K.L.B. BK IV
Pages 64-66
K.L.B. BK IV
Pages 67-68

ELECTRO-CHEMISTRY.

Redox reactions.
Oxidizing Numbers.

By the end of the lesson, the learner should be able to:


Describe redox reactions in terms of gain / loss of electrons.
Identify oxidizing / reducing agents involved in redox reactions.

Q/A: review cations, anions and charges.
Write down ionic half equations and identify reducing / oxidizing agents.

student book

K.L.B. BK IV
Pages 108-9

ELECTRO-CHEMISTRY.

Displacement reactions.

By the end of the lesson, the learner should be able to:
Explain change of oxidation numbers during redox / displacement reactions. Arrange elements in order of their reducing power.

Class standard experiments: reacting metals with solutions containing metal ions.
Taking note of reactions and those that do not take place; and tabulating the results.

Metals: Ca, Na, Zn, Fe, Pb, and Cu.
Solutions containing Ca2+, Mg2+, Zn2+, Fe2+.

K.L.B. BK IV
Pages 116-120

ELECTRO-CHEMISTRY.

Displacement reactions.

By the end of the lesson, the learner should be able to:
Explain change of oxidation numbers during redox / displacement reactions. Arrange elements in order of their reducing power.

Class standard experiments: reacting metals with solutions containing metal ions.
Taking note of reactions and those that do not take place; and tabulating the results.

Metals: Ca, Na, Zn, Fe, Pb, and Cu.
Solutions containing Ca2+, Mg2+, Zn2+, Fe2+.

K.L.B. BK IV
Pages 116-120

ELECTRO-CHEMISTRY.

The oxidizing power of an element.
Cell diagrams.
Standard Electrode Potentials.

By the end of the lesson, the learner should be able to:
Arrange elements in order of their oxidizing power.
Define the terms electrode, potential and e.m.f. of an electrochemical cell.
Describe components of a cell diagram.
Draw cell diagrams using correct notations.

Teacher demonstration / group expts:
Adding halogens to solutions containing halide ions.
Tabulate the results.
Discuss the results and arrive at the oxidizing power series of halogens.

Teacher demonstration: Zinc/ copper cell.
Q/A & discussion: changes in oxidation numbers.
Exposition: cell diagram and deducing the direction of electron flow.

Halogens:
Cl2 (g),
Br2 (l),
I2 (s).

Halides:
KCl, KBr, KI.
Zinc/ copper cell.
student book

K.L.B. BK IV
Pages 120-122
K.L.B. BK IV
Pages 123-128

ELECTRO-CHEMISTRY.

Standard electrode potential series.

By the end of the lesson, the learner should be able to:
Recall the order of standard electrode potentials.
Compare oxidizing and reducing powers of substances.

Q/A: review reactivity series, oxidizing agent, reducing agent.
Exposition: the order of standard electrode potentials.
Discussion: oxidizing and reducing powers of substances.

student book

K.L.B. BK IV
Pages 131-133

ELECTRO-CHEMISTRY.

Standard electrode potential series.

By the end of the lesson, the learner should be able to:
Recall the order of standard electrode potentials.
Compare oxidizing and reducing powers of substances.

Q/A: review reactivity series, oxidizing agent, reducing agent.
Exposition: the order of standard electrode potentials.
Discussion: oxidizing and reducing powers of substances.

student book

K.L.B. BK IV
Pages 131-133

ELECTRO-CHEMISTRY.

Emf of a cell.
Possibility of a reaction to take place.

By the end of the lesson, the learner should be able to:
Calculate emf of a cell using standard electrodes potentials.

Q/A: review half-cells.
Worked examples; supervised practice.
Assignment.

student book

K.L.B. BK IV
Pages 133-136

ELECTRO-CHEMISTRY.

Primary and secondary chemical cells.
Electrolysis of dilute NaCl.

By the end of the lesson, the learner should be able to:
Describe the functioning of primary and secondary chemical cells.
Define the term electrolysis.
Explain the concept of preferential discharge of ions.

Exposition of new concepts and brief discussion
Assignment.



Teacher demonstration: electrolysis of dilute sodium chloride with carbon electrodes.
Test for gases collected.
Write down equations of reactions at each electrode.
Discussion: preferential discharge of ions at electrodes.

student book
Dilute sodium chloride voltameter.

K.L.B. BK IV
Pages 138-141
K.L.B. BK IV
Pages 141-144

ELECTRO-CHEMISTRY.

Electrolysis of brine.

By the end of the lesson, the learner should be able to:
Identify products of electrolysis of brine.

Teacher demonstration/ group experiments.
Test for the products of electrolysis.
Write relevant equations.

Brine voltameter.

K.L.B. BK IV
Pages 144-146

ELECTRO-CHEMISTRY.

Electrolysis of dilute sulphuric (VI) acid.

By the end of the lesson, the learner should be able to:
Identify products of electrolysis of dilute sulphuric (VI) acid.

Teacher demonstration/ group experiments.
Test for the products of electrolysis.
Write relevant equations.

Sulphuric acid voltameter.

K.L.B. BK IV
Pages 146-148

ELECTRO-CHEMISTRY.

Factors affecting electrolysis.

By the end of the lesson, the learner should be able to:
Explain factors that affect electrolytic products discharged at electrodes.

Q/A: review the electrochemical series of elements.
Teacher writes down order of ease of discharge of ions at electrodes.
Discussion: other factors; giving suitable examples.

student book

K.L.B. BK IV
Pages 153-5

ELECTRO-CHEMISTRY.
ELECTRO-CHEMISTRY.
METALS

Application of electrolysis.
Faraday?s law of electrolysis.
Ores of some metals.

By the end of the lesson, the learner should be able to:
Describe some applications of electrolysis.
State Faraday?s law of electrolysis.
Solve problems related to Faraday?s law of electrolysis.

Probing questions and brief discussion on applications of electrolysis.
Practical assignment on electrolysis: electroplating an iron nail with a suitable metal.

Discuss above results, leading to Faraday?s law of electrolysis.

Worked examples.

Assignment.

Suitable voltameter.
Weighing balance, stop watch, copper sulphate voltameter.

K.L.B. BK IV
Pages 155-7
K.L.B. BK IV
Pages 161-4

METALS

Occurrence and extraction of sodium.

By the end of the lesson, the learner should be able to:
Describe occurrence and extraction of sodium.

Oral questions on electrolysis and equations at electrodes.
Brief discussion on occurrence and extraction.

Chart: Down?s cell.

K.L.B. BK IV
Pages 170-171

METALS

Occurrence and extraction of aluminium.

By the end of the lesson, the learner should be able to:
Describe occurrence and extraction of aluminium.

Brief discussion.
Write relevant chemical equations.

student book

K.L.B. BK IV
Pages 171-3

METALS

Occurrence and extraction of iron.

By the end of the lesson, the learner should be able to:
Describe occurrence and extraction of iron.

Brief discussion.
Write relevant chemical equations.

Chart: Blast furnace.

K.L.B. BK IV
Pages 173-5

METALS

Occurrence and extraction of zinc.
Extraction of lead.

By the end of the lesson, the learner should be able to:
Describe occurrence and extraction of zinc by electrolysis and reduction methods.

Explain how lead is extracted.

Brief discussion.
Write relevant chemical equations.
Q/A & brief discussion.
Write balanced chemical equations leading to extraction of lead.

Flow chart: extraction of Zinc.
Flow chart: extraction of lead.

K.L.B. BK IV
Pages 175-9
K.L.B. BK IV
Pages 179-80

METALS

Occurrence and extraction of copper.
Physical properties of some metals.

By the end of the lesson, the learner should be able to:
Describe extraction of copper.

Q/A & brief discussion.
Write balanced chemical equations leading to extraction of copper.

Flow chart: extraction of copper.
student book

K.L.B. BK IV
Pages 181-183

METALS

Reaction of metals with oxygen.

By the end of the lesson, the learner should be able to:
Explain effect of burning metals in air.

Teacher demonstration / Group experiments.
Burning some metals in air.
Write relevant equations.
Brief discussion.

Common lab. metals.

K.L.B. BK IV
Pages 184-6

METALS

Reaction of metals with oxygen.

By the end of the lesson, the learner should be able to:
Explain effect of burning metals in air.

Teacher demonstration / Group experiments.
Burning some metals in air.
Write relevant equations.
Brief discussion.

Common lab. metals.

K.L.B. BK IV
Pages 184-6

METALS

Reaction of metals with cold water and steam.

By the end of the lesson, the learner should be able to:
Describe reaction of metals with cold water and steam.

Arrange the metals in order of reactivity with cold water and steam.

Class experiments:
Investigate reaction of some metals with cold water and steam.
Analyse the results.

Metals: Al, Zn, Fe, Cu.

K.L.B. BK IV
Pages 186-9

METALS

Reaction of metals with chlorine.

By the end of the lesson, the learner should be able to:
Describe the reaction of metals with chlorine.

Teacher demonstration in a fume cupboard / in the open.
Investigate reaction of metals with chorine
Write corresponding equations.

Metals: Al, Zn, Fe, Cu.

K.L.B. BK IV
Pages 189-191

METALS

Reaction of metals with acids.

By the end of the lesson, the learner should be able to:
Describe and explain reaction of metals with acids.

Group experiments: investigate reaction of metals with dilute acids.
Teacher demonstration: investigate reaction of metals with concentrated acids.
Discuss the observations made and write relevant chemical equations.

Metals: Al, Zn, Fe, Cu.

Acids; HCl, HNO3, H2SO4.

K.L.B. BK IV
Pages 191-4

METALS

Uses of metals.

By the end of the lesson, the learner should be able to:
State uses of some metals and alloys.

Q/A & brief discussion;
Uses of Sodium, Aluminium, Zinc, Iron and Copper & some alloys.

student book

K.L.B. BK IV
Pages 194-7

METALS
ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Environmental effects of extraction of metals.
Alkanols (Alcohols).

By the end of the lesson, the learner should be able to:
Identify some environmental effects of extraction of metals.



Identify the functional group of alkanols.

Explain formation of alkanol molecules.

Oral questions and open discussion.

Assignment / Topic review.



Q/A: review alkanes, alkenes and alkynes.

Teacher exposes new concepts and links them with already known concepts.

student book

K.L.B. BK IV
Pages 197-8
K.L.B. BK IV
Page 205

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Nomenclature of alkanols.
Isomerism in alkanols.

By the end of the lesson, the learner should be able to:
Name and draw the structure of simple alkanols.

Guided discovery of naming system for alkanols.
Draw and name structures of alkanols.

student book

K.L.B. BK IV
Pages 206-8

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Preparation of ethanol in the lab.

By the end of the lesson, the learner should be able to:
Describe preparation of ethanol in the laboratory.

Group experiments / teacher demonstration.

Discuss the fermentation process.

Calcium hydroxide solution, sugar solution, yeast.

K.L.B. BK IV
Pages 210-11

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Preparation of ethanol in the lab.

By the end of the lesson, the learner should be able to:
Describe preparation of ethanol in the laboratory.

Group experiments / teacher demonstration.

Discuss the fermentation process.

Calcium hydroxide solution, sugar solution, yeast.

K.L.B. BK IV
Pages 210-11