ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Endothermic and Exothermic Reactions.
Energy level diagrams.

By the end of the lesson, the learner should be able to:






To differentiate between endothermic & exothermic reactions.

Investigate temperature changes in solution formation.

Obtain changes in temperature when ammonium nitrate and sodium hydroxide are dissolved in water, one at a time.

Ammonium nitrate,
Sodium hydroxide, thermometers.
student book

K.L.B. BK IV
Pages 32-33

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Enthalpy Notation. Change of state.

By the end of the lesson, the learner should be able to:
Define the term enthalpy.
Distinguish positive enthalpy change from negative enthalpy change.

Determine the M.P/ B.P of a pure substance.

Q/A and brief discussion.
Class experiments: determine B.P of pure water/ M.P of naphthalene / ice.
Use experimental results to plot temperature-time graphs.
Explain the shape of the graphs.
Q/A: review kinetic theory of matter.
Apply the theory to explain the shape of the graph, and nature of bonding in substances.

Ice, naphthalene, thermometers, graph papers.

K.L.B. BK IV
Pages 35-39

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution.
Molar heat of solution of H2SO4.

By the end of the lesson, the learner should be able to:
Determine molar heat of solution of given substances.
Determine molar heat of solution of H2SO4.

Dissolve known masses of ammonia nitrate / sodium hydroxide in known volumes of water.
Determine temperature changes.
Calculate molar heat of solution. Supervised practice.


Dissolve some known volume of conc. H2SO4 in a given volume of water.
Note the change in temperature.
Work out the molar heat of solution of H2SO4.

Ammonia nitrate / sodium hydroxide, thermometers.
Conc. H2SO4, thermometers.

K.L.B. BK IV
Pages 40-41
K.L.B. BK IV
Pages 42-45

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Enthalpy of combustion. Enthalpy of combustion.

By the end of the lesson, the learner should be able to:
Define the term enthalpy of combustion.
Determine the enthalpy of combustion of ethanol.
Explain why actual heats of combustion are usually lower than the theoretical values.

Group experiments / teacher demonstration.

Obtain and record results.


Work out calculations.

Ethanol, distilled water, thermometer, clear wick, tripod stand and wire gauze.

K.L.B. BK IV
Pages 45-48

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of displacement of ions.

By the end of the lesson, the learner should be able to:
Define the term molar heat of solution of displacement of ions.
Determine the molar heat of solution of displacement of ions.

Group experiments/ teacher demonstration.
Note steady temperature of solutions formed when zinc/ iron / magnesium reacts with copper sulphate solution.
Work out the molar heat of displacement of a substance from a solution of its ions.

Zinc, iron, magnesium, copper sulphate solution.

K.L.B. BK IV
Pages 48-50

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of neutralization.

By the end of the lesson, the learner should be able to:
Define the term neutralization.
Determine the molar heat of neutralization of HCl with NaOH.

Class experiments:
Neutralize 2M HCl of known volume with a determined volume of 1M / 2M sodium hydroxide.
Note highest temperature of the solution.
Work out the molar heat of neutralization.
Solve other related problems.
Assignment.

2M HCl of known volume, 1M / 2M sodium hydroxide.

K.L.B. BK IV
Pages 50-53

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Standard enthalpy changes.
Hess?s Law.

By the end of the lesson, the learner should be able to:
Define the term standard enthalpy change.
Denote standard enthalpy change with the correct notation.

State Hess?s law.

Solve problems related to Hess?s law.

Exposition & brief discussion.
Detailed discussion & guided discovery of the law.
Illustrations of energy cycles and energy levels leading to Hess?s law.
Worked examples.
Supervised practice
Written assignment.

student book

K.L.B. BK IV
Pages 54-56
K.L.B. BK IV
Pages 56-57

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Heat of solution hydration energy and lattice energy.

By the end of the lesson, the learner should be able to:
Define the terms lattice energy and hydration energy.
Explain the relationship between heat of solution, hydration energy.
Solve related problems.

Exposition of new concepts.
Guided discovery of the relationship between heat solution hydration energy and lattice energy.
Worked examples.
Assignment.

student book

K.L.B. BK IV
Pages 60-64

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Heat values of fuels.

By the end of the lesson, the learner should be able to:
Define the term fuel.
Describe energy changes when a fuel undergoes combustion.
Outline factors considered when choosing a suitable fuel.

Probing questions and brief discussion.

student book

K.L.B. BK IV
Pages 64-66

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.
ELECTRO-CHEMISTRY.

Environmental effects of fuels.
Redox reactions.

By the end of the lesson, the learner should be able to:
Outline some environmental effects of fuels.
Identify measures taken to reduce environmental
pollution.

Q/A & open discussion.

student book

K.L.B. BK IV
Pages 67-68

ELECTRO-CHEMISTRY.

Oxidizing Numbers.
Displacement reactions.

By the end of the lesson, the learner should be able to:
Outline rules of assigning oxidation numbers.
Determine the oxidation numbers of an element in a given compound.
Explain the use of oxidation numbers in naming compounds.
Explain change of oxidation numbers during redox / displacement reactions. Arrange elements in order of their reducing power.

Exposition and giving specific examples.
Work out oxidizing number of elements in given compounds.
Copy and complete a table of compounds containing elements that more than one oxidation number.

Class standard experiments: reacting metals with solutions containing metal ions.
Taking note of reactions and those that do not take place; and tabulating the results.

student book
Metals: Ca, Na, Zn, Fe, Pb, and Cu.
Solutions containing Ca2+, Mg2+, Zn2+, Fe2+.

K.L.B. BK IV
Pages 109-116
K.L.B. BK IV
Pages 116-120

ELECTRO-CHEMISTRY.

The oxidizing power of an element.
Cell diagrams.

By the end of the lesson, the learner should be able to:
Arrange elements in order of their oxidizing power.

Teacher demonstration / group expts:
Adding halogens to solutions containing halide ions.
Tabulate the results.
Discuss the results and arrive at the oxidizing power series of halogens.

Halogens:
Cl2 (g),
Br2 (l),
I2 (s).
Halides:
KCl, KBr, KI.
Zinc/ copper cell.

K.L.B. BK IV
Pages 120-122

ELECTRO-CHEMISTRY.

Standard Electrode Potentials.

By the end of the lesson, the learner should be able to:
Identify standard conditions for measuring electrode potentials.
Define the term standard electrode potential of a cell.
Write half reactions of electrochemical cells.

Descriptive and expository approaches: teacher exposes new concepts.

student book

K.L.B. BK IV
Pages 129-131

ELECTRO-CHEMISTRY.

Standard electrode potential series.

By the end of the lesson, the learner should be able to:
Recall the order of standard electrode potentials.
Compare oxidizing and reducing powers of substances.

Q/A: review reactivity series, oxidizing agent, reducing agent.
Exposition: the order of standard electrode potentials.
Discussion: oxidizing and reducing powers of substances.

student book

K.L.B. BK IV
Pages 131-133

ELECTRO-CHEMISTRY.

Emf of a cell.
Possibility of a reaction to take place.
Primary and secondary chemical cells.

By the end of the lesson, the learner should be able to:
Calculate emf of a cell using standard electrodes potentials.
Describe the functioning of primary and secondary chemical cells.

Q/A: review half-cells.
Worked examples; supervised practice.
Assignment.

Exposition of new concepts and brief discussion
Assignment.

student book

K.L.B. BK IV
Pages 133-136
K.L.B. BK IV
Pages 138-141

ELECTRO-CHEMISTRY.

Electrolysis of dilute NaCl.

By the end of the lesson, the learner should be able to:
Define the term electrolysis.
Explain the concept of preferential discharge of ions.

Teacher demonstration: electrolysis of dilute sodium chloride with carbon electrodes.
Test for gases collected.
Write down equations of reactions at each electrode.
Discussion: preferential discharge of ions at electrodes.

Dilute sodium chloride voltameter.

K.L.B. BK IV
Pages 141-144

ELECTRO-CHEMISTRY.

Electrolysis of brine.
Electrolysis of dilute sulphuric (VI) acid.

By the end of the lesson, the learner should be able to:
Identify products of electrolysis of brine.

Teacher demonstration/ group experiments.
Test for the products of electrolysis.
Write relevant equations.

Brine voltameter.
Sulphuric acid voltameter.

K.L.B. BK IV
Pages 144-146

ELECTRO-CHEMISTRY.

Factors affecting electrolysis.

By the end of the lesson, the learner should be able to:
Explain factors that affect electrolytic products discharged at electrodes.

Q/A: review the electrochemical series of elements.
Teacher writes down order of ease of discharge of ions at electrodes.
Discussion: other factors; giving suitable examples.

student book

K.L.B. BK IV
Pages 153-5

ELECTRO-CHEMISTRY.
METALS

Application of electrolysis.
Faraday?s law of electrolysis.
Ores of some metals.

By the end of the lesson, the learner should be able to:
Describe some applications of electrolysis.


Name the chief ores of some metals.

Probing questions and brief discussion on applications of electrolysis.
Practical assignment on electrolysis: electroplating an iron nail with a suitable metal.



Exposition and brief discussion.

Suitable voltameter.
Weighing balance, stop watch, copper sulphate voltameter.

K.L.B. BK IV
Pages 155-7
K.L.B. BK IV
Pages 168-9

METALS

Occurrence and extraction of sodium.
Occurrence and extraction of aluminium.

By the end of the lesson, the learner should be able to:
Describe occurrence and extraction of sodium.

Oral questions on electrolysis and equations at electrodes.
Brief discussion on occurrence and extraction.

Chart: Down?s cell.
student book

K.L.B. BK IV
Pages 170-171

METALS

Occurrence and extraction of iron.

By the end of the lesson, the learner should be able to:
Describe occurrence and extraction of iron.

Brief discussion.
Write relevant chemical equations.

Chart: Blast furnace.

K.L.B. BK IV
Pages 173-5

METALS

Occurrence and extraction of zinc.

By the end of the lesson, the learner should be able to:
Describe occurrence and extraction of zinc by electrolysis and reduction methods.

Brief discussion.
Write relevant chemical equations.

Flow chart: extraction of Zinc.

K.L.B. BK IV
Pages 175-9

METALS

Extraction of lead.

By the end of the lesson, the learner should be able to:
Explain how lead is extracted.

Q/A & brief discussion.
Write balanced chemical equations leading to extraction of lead.

Flow chart: extraction of lead.

K.L.B. BK IV
Pages 179-80

METALS

Occurrence and extraction of copper.
Physical properties of some metals.

By the end of the lesson, the learner should be able to:
Describe extraction of copper.

Q/A & brief discussion.
Write balanced chemical equations leading to extraction of copper.

Flow chart: extraction of copper.
student book

K.L.B. BK IV
Pages 181-183

METALS

Reaction of metals with oxygen.
Reaction of metals with cold water and steam.

By the end of the lesson, the learner should be able to:
Explain effect of burning metals in air.
Describe reaction of metals with cold water and steam.

Arrange the metals in order of reactivity with cold water and steam.

Teacher demonstration / Group experiments.
Burning some metals in air.
Write relevant equations.
Brief discussion.

Class experiments:
Investigate reaction of some metals with cold water and steam.
Analyse the results.

Common lab. metals.
Metals: Al, Zn, Fe, Cu.

K.L.B. BK IV
Pages 184-6
K.L.B. BK IV
Pages 186-9

METALS

Reaction of metals with chlorine.

By the end of the lesson, the learner should be able to:
Describe the reaction of metals with chlorine.

Teacher demonstration in a fume cupboard / in the open.
Investigate reaction of metals with chorine
Write corresponding equations.

Metals: Al, Zn, Fe, Cu.

K.L.B. BK IV
Pages 189-191

METALS

Reaction of metals with acids.

By the end of the lesson, the learner should be able to:
Describe and explain reaction of metals with acids.

Group experiments: investigate reaction of metals with dilute acids.
Teacher demonstration: investigate reaction of metals with concentrated acids.
Discuss the observations made and write relevant chemical equations.

Metals: Al, Zn, Fe, Cu.

Acids; HCl, HNO3, H2SO4.

K.L.B. BK IV
Pages 191-4

METALS

Uses of metals.

By the end of the lesson, the learner should be able to:
State uses of some metals and alloys.

Q/A & brief discussion;
Uses of Sodium, Aluminium, Zinc, Iron and Copper & some alloys.

student book

K.L.B. BK IV
Pages 194-7

METALS
ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Environmental effects of extraction of metals.
Alkanols (Alcohols).
Nomenclature of alkanols.

By the end of the lesson, the learner should be able to:
Identify some environmental effects of extraction of metals.
Name and draw the structure of simple alkanols.

Oral questions and open discussion.

Assignment / Topic review.
Guided discovery of naming system for alkanols.
Draw and name structures of alkanols.

student book

K.L.B. BK IV
Pages 197-8
K.L.B. BK IV
Pages 206-8

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Isomerism in alkanols.

By the end of the lesson, the learner should be able to:
Describe positional and chain isomerism in alkanols.
Explain formation of primary and secondary alkanols.

Q/A: review the terms positional and chain isomerism.
Brief discussion on isomerism.
Oral exercise: naming given organic compounds.
Written exercise: writing structural formulae for isomers of organic compounds of a given molecular formula.

student book

K.L.B. BK IV
Pages 208-10

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Preparation of ethanol in the lab.
Physical properties of alkanols.

By the end of the lesson, the learner should be able to:
Describe preparation of ethanol in the laboratory.

Group experiments / teacher demonstration.

Discuss the fermentation process.

Calcium hydroxide solution, sugar solution, yeast.
student book

K.L.B. BK IV
Pages 210-11

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Chemical properties of alkanols.

By the end of the lesson, the learner should be able to:
Describe some chemical reactions of alkanols.

Group experiments/ teacher demonstration to investigate combustion of ethanol and its reaction with metals.
Write corresponding chemical equations.

student book

K.L.B. BK IV
Pages 213-5

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Esters and esterification.
Oxidation of ethanol. Uses of alkanols.
Alkanoic (Carboxylic Acids).

By the end of the lesson, the learner should be able to:
Explain formation of esters.
Describe the esterification process.

Explain oxidation of ethanol by an oxidizing agent.
State uses of alkanols.
Explain the effects of alcohol on human health

Teacher exposes and explains new concepts.

Assignment.
Q/A: review redox reactions, oxidizing and reducing agents.
Brief discussion: oxidation of ethanol using potassium (VII) manganate or potassium (VI) dichromate.
Write corresponding chemical equations.
Open discussion.

student book

K.L.B. BK IV
Pages 215-6
K.L.B. BK IV
Pages 216-8

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Nomenclature of alkanoic acids.

By the end of the lesson, the learner should be able to:
Name and draw the structure of simple alkanoic acids.

Guided discovery of the naming system for alkanoic acids.

Chart: homologous series of alkanoic acids.

K.L.B. BK IV
Pages 219-221

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Lab preparation of ethanoic acid.

By the end of the lesson, the learner should be able to:
Describe laboratory preparation of ethanoic acid.

Teacher demonstration: prepare ethanoic acid in the lab.

Brief discussion on preparation of ethanoic acid.

Concentrated H2SO4, potassium manganate
(VII) Crystals, water bath.

K.L.B. BK IV
Pages 221-223

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Physical properties of alkanoic acids.

By the end of the lesson, the learner should be able to:
Explain some physical properties of alkanoic acids.

Compare physical properties of some alkanoic acids.
Discuss the difference in physical properties among alkanoic acids.

student book

K.L.B. BK IV
Pages 223-4

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Chemical properties of alkanoic acids.
Chemical properties & Uses of alkanoic acids.
Soap preparation in the lab.

By the end of the lesson, the learner should be able to:
Explain some chemical properties of alkanoic acids.
Write equations for chemical reactions involving acids.
State uses of alkanoic acids.

Group experiment: investigate some chemical properties of ethanoic acid.
Carry out tests and record observations in a table.
Review and discuss the observations above.
Write corresponding chemical equations.
Teacher elucidates uses of alkanoic acids.

Ethanoic acid, universal indicator, sodium carbonate, magnesium strip, ethanol, conc. H2SO4 and sodium hydroxide.

student book

K.L.B. BK IV
Pages 224-5
K.L.B. BK IV
Pages 225-7

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Cleaning action of soap.

By the end of the lesson, the learner should be able to:
Describe the nature of a soap molecule.
Explain the mode of action in cleaning.

Expository and descriptive approaches.
Answer oral questions.

student book

K.L.B. BK IV
Pages 230-232

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Effects of hard / soft water on soap.
Soapless detergents.

By the end of the lesson, the learner should be able to:
Explain the effects of hard/ soft water on soap.

Group experiments: form soap lather in different solutions.

Deduce the effects of hard/ soft water on soap.

Distilled water, tap water, rainwater, sodium chloride solution.
Calcium nitrate, Zinc Sulphate, etc.
student book

K.L.B. BK IV
Pages 232-235

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Polymers and polymerization.

By the end of the lesson, the learner should be able to:
Explain the concepts additional and condensation polymerization as methods of making synthetic polymers.
Identify some products of polymerization.
State merits and demerits of synthetic polymers over natural materials.

Teacher exposes and explains new concepts.

Detailed discussion.

Assignment.

student book

K.L.B. BK IV
Pages 238-242

RADIOACTIVITY

Definition of radioactivity.
Alpha particles.
Equations involving alpha particles.
Beta particles. Gamma rays.
Radioactive Half-Life.

By the end of the lesson, the learner should be able to:


Define radioactivity, a nuclide and radioactive decay.
Differentiate between natural and artificial radioactivity.


Write down and balance equations involving alpha particles.

Q/A: Review the atomic structure.
Exposition: symbolic representation of an atom / nucleus.
Exposition: meaning of radioactivity and radioactive decay.
Discussion: artificial and natural radioactivity.


Q/A: Review atomic and mass numbers.
Examples of balanced equations.
Supervised practice.

student book
student book
Dice.

K.L.B. BK IV
Pages 249-251
K.L.B. BK IV
Page 257

RADIOACTIVITY

Radioactive decay curve.
Nuclear fusion and nuclear fission. Applications of radioactivity.

By the end of the lesson, the learner should be able to:
Plot a radioactive decay curve to deduce the
half ?life from the curve.

Drawing a radioactive decay curve inferring the half-life of the sample from the graph.

Graph papers.
student book

K.L.B. BK IV
Pages 254-5