ORGANIC CHEMISTRY II

Introduction to Alkanols and Nomenclature
Isomerism in Alkanols

By the end of the lesson, the learner should be able to:
Define alkanols and identify functional group
- Apply nomenclature rules for alkanols
- Draw structural formulae of simple alkanols
- Compare alkanols with corresponding alkanes
Explain positional and chain isomerism
- Draw isomers of given alkanols
- Name different isomeric forms
- Classify isomers as primary, secondary, or tertiary

Q/A: Review alkanes, alkenes from Form 3
- Study functional group -OH concept
- Practice naming alkanols using IUPAC rules
- Complete Table 6.2 - alkanol structures
Study positional isomerism examples (propan-1-ol vs propan-2-ol)
- Practice drawing chain isomers
- Exercises on isomer identification and naming
- Discussion on structural differences

Molecular models, Table 6.1 and 6.2, alkanol structure charts, student books
Isomer structure charts, molecular models, practice worksheets, student books

KLB Secondary Chemistry Form 4, Pages 167-170
KLB Secondary Chemistry Form 4, Pages 170-171

ORGANIC CHEMISTRY II

Laboratory Preparation of Ethanol

By the end of the lesson, the learner should be able to:
Describe fermentation process
- Prepare ethanol in laboratory
- Write equation for glucose fermentation
- Explain role of yeast and conditions needed

Experiment 6.1: Fermentation of sugar solution with yeast
- Set up apparatus for 2-3 days
- Observe gas evolution
- Test for CO₂ with lime water
- Smell final product

Sugar, yeast, warm water, conical flask, delivery tube, lime water, thermometer

KLB Secondary Chemistry Form 4, Pages 171-172

ORGANIC CHEMISTRY II

Industrial Preparation and Physical Properties
Chemical Properties of Alkanols I

By the end of the lesson, the learner should be able to:
Explain hydration of ethene method
- Compare laboratory and industrial methods
- Analyze physical properties of alkanols
- Relate properties to molecular structure

Study ethene hydration using phosphoric acid catalyst
- Compare fermentation vs industrial methods
- Analyze Table 6.3 - physical properties
- Discussion on hydrogen bonding effects

Table 6.3, industrial process diagrams, ethene structure models, property comparison charts
Ethanol, sodium metal, universal indicator, concentrated H₂SO₄, ethanoic acid, test tubes

KLB Secondary Chemistry Form 4, Pages 171-173

ORGANIC CHEMISTRY II

Chemical Properties of Alkanols II

By the end of the lesson, the learner should be able to:
Investigate oxidation and esterification reactions
- Test oxidizing agents on ethanol
- Prepare esters from alkanols
- Explain dehydration reactions

Complete Experiment 6.2: Test with acidified K₂Cr₂O₇ and KMnO₄
- Observe color changes
- Esterification with ethanoic acid
- Study dehydration conditions

Acidified potassium chromate/manganate, ethanoic acid, concentrated H₂SO₄, heating apparatus

KLB Secondary Chemistry Form 4, Pages 173-176

ORGANIC CHEMISTRY II

Uses of Alkanols and Health Effects
Introduction to Alkanoic Acids

By the end of the lesson, the learner should be able to:
State various uses of alkanols
- Explain health effects of alcohol consumption
- Discuss methylated spirits
- Analyze alcohol in society
Define alkanoic acids and functional group
- Apply nomenclature rules
- Draw structural formulae
- Compare with alkanols

Discussion on alkanol applications as solvents, fuels, antiseptics
- Health effects of alcohol consumption
- Methylated spirits composition
- Social implications
Study carboxyl group (-COOH) structure
- Practice naming using IUPAC rules
- Complete Table 6.5 and 6.6
- Compare functional groups of alkanols and acids

Charts showing alkanol uses, health impact data, methylated spirit samples, discussion materials
Alkanoic acid structure charts, Table 6.5 and 6.6, molecular models, student books

KLB Secondary Chemistry Form 4, Pages 176-177
KLB Secondary Chemistry Form 4, Pages 177-179

ORGANIC CHEMISTRY II

Laboratory Preparation of Ethanoic Acid

By the end of the lesson, the learner should be able to:
Prepare ethanoic acid by oxidation
- Write equations for preparation
- Set up oxidation apparatus
- Identify product by testing

Experiment 6.3: Oxidize ethanol using acidified KMnO₄
- Set up heating and distillation apparatus
- Collect distillate at 118°C
- Test product properties

Ethanol, KMnO₄, concentrated H₂SO₄, distillation apparatus, thermometer, round-bottom flask

KLB Secondary Chemistry Form 4, Pages 179-180

ORGANIC CHEMISTRY II

Physical and Chemical Properties of Alkanoic Acids

By the end of the lesson, the learner should be able to:
Investigate chemical reactions of ethanoic acid
- Test with various reagents
- Write chemical equations
- Analyze acid strength

Experiment following Table 6.8: Test ethanoic acid with indicators, metals, carbonates, bases
- Record observations
- Write equations
- Discuss weak acid behavior

2M ethanoic acid, universal indicator, Mg strip, Na₂CO₃, NaOH, phenolphthalein, test tubes

KLB Secondary Chemistry Form 4, Pages 180-182

ORGANIC CHEMISTRY II

Physical and Chemical Properties of Alkanoic Acids

By the end of the lesson, the learner should be able to:
Investigate chemical reactions of ethanoic acid
- Test with various reagents
- Write chemical equations
- Analyze acid strength

Experiment following Table 6.8: Test ethanoic acid with indicators, metals, carbonates, bases
- Record observations
- Write equations
- Discuss weak acid behavior

2M ethanoic acid, universal indicator, Mg strip, Na₂CO₃, NaOH, phenolphthalein, test tubes

KLB Secondary Chemistry Form 4, Pages 180-182

ORGANIC CHEMISTRY II

Esterification and Uses of Alkanoic Acids

By the end of the lesson, the learner should be able to:
Explain ester formation process
- Write esterification equations
- State uses of alkanoic acids
- Prepare simple esters

Complete esterification experiments
- Study concentrated H₂SO₄ as catalyst
- Write general esterification equation
- Discuss applications in food, drugs, synthetic fibres

Ethanoic acid, ethanol, concentrated H₂SO₄, test tubes, heating apparatus, cold water

KLB Secondary Chemistry Form 4, Pages 182-183

ORGANIC CHEMISTRY II

Introduction to Detergents and Soap Preparation

By the end of the lesson, the learner should be able to:
Define detergents and classify types
- Explain saponification process
- Prepare soap in laboratory
- Compare soapy and soapless detergents

Study soap vs soapless detergent differences
- Experiment 6.5: Saponify castor oil with NaOH
- Add salt for salting out
- Test soap formation

Castor oil, 4M NaOH, NaCl, evaporating dish, water bath, stirring rod, filter paper

KLB Secondary Chemistry Form 4, Pages 183-186

ORGANIC CHEMISTRY II

Mode of Action of Soap and Hard Water Effects

By the end of the lesson, the learner should be able to:
Explain soap molecule structure
- Describe cleaning mechanism
- Investigate hard water effects
- Compare soap performance in different waters

Study hydrophobic and hydrophilic ends
- Demonstrate micelle formation
- Test soap in distilled vs hard water
- Observe scum formation
- Write precipitation equations

Soap samples, distilled water, hard water (CaCl₂/MgSO₄ solutions), test tubes, demonstration materials

KLB Secondary Chemistry Form 4, Pages 186-188

ORGANIC CHEMISTRY II

Mode of Action of Soap and Hard Water Effects

By the end of the lesson, the learner should be able to:
Explain soap molecule structure
- Describe cleaning mechanism
- Investigate hard water effects
- Compare soap performance in different waters

Study hydrophobic and hydrophilic ends
- Demonstrate micelle formation
- Test soap in distilled vs hard water
- Observe scum formation
- Write precipitation equations

Soap samples, distilled water, hard water (CaCl₂/MgSO₄ solutions), test tubes, demonstration materials

KLB Secondary Chemistry Form 4, Pages 186-188

ORGANIC CHEMISTRY II

Soapless Detergents and Environmental Effects

By the end of the lesson, the learner should be able to:
Explain soapless detergent preparation
- Compare advantages/disadvantages
- Discuss environmental impact
- Analyze pollution effects

Study alkylbenzene sulphonate preparation
- Compare Table 6.9 - soap vs soapless
- Discussion on eutrophication and biodegradability
- Environmental awareness

Flow charts of detergent manufacture, Table 6.9, environmental impact data, sample detergents

KLB Secondary Chemistry Form 4, Pages 188-191

ORGANIC CHEMISTRY II

Introduction to Polymers and Addition Polymerization

By the end of the lesson, the learner should be able to:
Define polymers, monomers, and polymerization
- Explain addition polymerization
- Draw polymer structures
- Calculate polymer properties

Study polymer concept and terminology
- Practice drawing addition polymers from monomers
- Examples: polyethene, polypropene, PVC
- Calculate molecular masses

Polymer samples, monomer structure charts, molecular models, calculators, polymer formation diagrams

KLB Secondary Chemistry Form 4, Pages 191-195

ORGANIC CHEMISTRY II

Addition Polymers - Types and Properties

By the end of the lesson, the learner should be able to:
Identify different addition polymers
- Draw structures from monomers
- Name common polymers
- Relate structure to properties

Study polystyrene, PTFE, perspex formation
- Practice identifying monomers from polymer structures
- Work through polymer calculation examples
- Properties analysis

Various polymer samples, structure identification exercises, calculation worksheets, Table 6.10

KLB Secondary Chemistry Form 4, Pages 195-197

ORGANIC CHEMISTRY II

Addition Polymers - Types and Properties

By the end of the lesson, the learner should be able to:
Identify different addition polymers
- Draw structures from monomers
- Name common polymers
- Relate structure to properties

Study polystyrene, PTFE, perspex formation
- Practice identifying monomers from polymer structures
- Work through polymer calculation examples
- Properties analysis

Various polymer samples, structure identification exercises, calculation worksheets, Table 6.10

KLB Secondary Chemistry Form 4, Pages 195-197

ORGANIC CHEMISTRY II

Condensation Polymerization and Natural Polymers

By the end of the lesson, the learner should be able to:
Explain condensation polymerization
- Compare with addition polymerization
- Study natural polymers
- Analyze nylon formation

Study nylon 6,6 formation from diamine and dioic acid
- Natural polymers: starch, protein, rubber
- Vulcanization process
- Compare synthetic vs natural

Nylon samples, rubber samples, condensation reaction diagrams, natural polymer examples

KLB Secondary Chemistry Form 4, Pages 197-200

ORGANIC CHEMISTRY II

Condensation Polymerization and Natural Polymers

By the end of the lesson, the learner should be able to:
Explain condensation polymerization
- Compare with addition polymerization
- Study natural polymers
- Analyze nylon formation

Study nylon 6,6 formation from diamine and dioic acid
- Natural polymers: starch, protein, rubber
- Vulcanization process
- Compare synthetic vs natural

Nylon samples, rubber samples, condensation reaction diagrams, natural polymer examples

KLB Secondary Chemistry Form 4, Pages 197-200

ORGANIC CHEMISTRY II

Polymer Properties and Applications

By the end of the lesson, the learner should be able to:
Compare advantages and disadvantages of synthetic polymers
- State uses of different polymers
- Discuss environmental concerns
- Analyze polymer selection

Study Table 6.10 - polymer uses
- Advantages: strength, lightness, moldability
- Disadvantages: non-biodegradability, toxic gases
- Application analysis

Table 6.10, polymer application samples, environmental impact studies, product examples

KLB Secondary Chemistry Form 4, Pages 200-201

ORGANIC CHEMISTRY II

Comprehensive Problem Solving and Integration

By the end of the lesson, the learner should be able to:
Solve complex problems involving alkanols and acids
- Apply knowledge to practical situations
- Integrate polymer concepts
- Practice examination questions

Worked examples on organic synthesis
- Problem-solving on isomers, reactions, polymers
- Integration of all unit concepts
- Practice examination-style questions

Comprehensive problem sets, past examination papers, calculators, organic chemistry summary charts

KLB Secondary Chemistry Form 4, Pages 167-201

ACIDS, BASES AND SALTS

Definition of Acids

By the end of the lesson, the learner should be able to:
- Define an acid in terms of hydrogen ions
-Investigate reactions of magnesium and zinc carbonate with different acids
-Write equations for reactions taking place
-Explain why magnesium strip should be cleaned

Class experiment: React cleaned magnesium strips with 2M HCl, 2M ethanoic acid, 2M H₂SO₄, 2M ethanedioic acid. Record observations in table. Repeat using zinc carbonate. Write chemical equations. Discuss hydrogen ion displacement and gas evolution.

Magnesium strips, zinc carbonate, 2M HCl, 2M ethanoic acid, 2M H₂SO₄, 2M ethanedioic acid, test tubes, test tube rack

KLB Secondary Chemistry Form 4, Pages 1-3

ACIDS, BASES AND SALTS

Definition of Acids

By the end of the lesson, the learner should be able to:
- Define an acid in terms of hydrogen ions
-Investigate reactions of magnesium and zinc carbonate with different acids
-Write equations for reactions taking place
-Explain why magnesium strip should be cleaned

Class experiment: React cleaned magnesium strips with 2M HCl, 2M ethanoic acid, 2M H₂SO₄, 2M ethanedioic acid. Record observations in table. Repeat using zinc carbonate. Write chemical equations. Discuss hydrogen ion displacement and gas evolution.

Magnesium strips, zinc carbonate, 2M HCl, 2M ethanoic acid, 2M H₂SO₄, 2M ethanedioic acid, test tubes, test tube rack

KLB Secondary Chemistry Form 4, Pages 1-3

ACIDS, BASES AND SALTS

Strength of Acids
Definition of Bases
Strength of Bases

By the end of the lesson, the learner should be able to:
- Compare strengths of acids using pH values
-Determine strengths of acids by comparing their electrical conductivity
-Classify acids as either strong or weak
-Explain complete and partial dissociation of acids
- Compare strengths of bases using pH values
-Determine strengths of bases by comparing their electrical conductivity
-Classify bases as either strong or weak
-Explain complete and partial ionization of bases

Class experiment: Test pH of 2M HCl and 2M ethanoic acid using universal indicator. Set up electrical conductivity apparatus with both acids. Record milliammeter readings. Compare results and explain in terms of hydrogen ion concentration. Discuss strong vs weak acid definitions.
Class experiment: Test pH of 2M NaOH and 2M ammonia solution using universal indicator. Test electrical conductivity of both solutions using same apparatus as acids. Compare deflections and pH values. Explain in terms of OH⁻ ion concentration and complete vs partial ionization.

2M HCl, 2M ethanoic acid, universal indicator, pH chart, electrical conductivity apparatus, milliammeter, carbon electrodes, beakers, wires
Calcium hydroxide, red litmus paper, phenolphthalein indicator, distilled water, test tubes, spatula, evaporating dish
2M NaOH, 2M ammonia solution, universal indicator, pH chart, electrical conductivity apparatus, milliammeter, carbon electrodes

KLB Secondary Chemistry Form 4, Pages 3-5
KLB Secondary Chemistry Form 4, Pages 5-7

ACIDS, BASES AND SALTS

Acid-Base Reactions

By the end of the lesson, the learner should be able to:
- Write equations for acid-base reactions
-Explain neutralization process
-Identify products of acid-base reactions
-Demonstrate formation of salt and water

Q/A: Review acid and base definitions. Demonstrate neutralization reactions: HCl + NaOH, H₂SO₄ + Ca(OH)₂, HNO₃ + KOH. Write molecular and ionic equations. Explain H⁺ + OH⁻ → H₂O. Discuss salt formation. Use indicators to show neutralization point.

Various acids and bases from previous lessons, indicators, beakers, measuring cylinders, stirring rods

KLB Secondary Chemistry Form 4, Pages 6-7

ACIDS, BASES AND SALTS

Effect of Solvent on Acids

By the end of the lesson, the learner should be able to:
- Explain effect of polar and non-polar solvents on hydrogen chloride
-Investigate HCl behavior in water vs methylbenzene
-Define polar and non-polar solvents
-Explain why acids show properties only in polar solvents

Teacher demonstration: Dissolve HCl gas in water and methylbenzene separately. Test both solutions with litmus paper, magnesium, and calcium carbonate. Compare observations. Explain polarity of water vs methylbenzene. Discuss dissociation vs molecular solution.

HCl gas, distilled water, methylbenzene, magnesium ribbon, calcium carbonate, litmus paper, test tubes, gas absorption apparatus

KLB Secondary Chemistry Form 4, Pages 7-9

ACIDS, BASES AND SALTS

Effect of Solvent on Bases

By the end of the lesson, the learner should be able to:
- Investigate effect of polar and non-polar solvents on ammonia gas
-Compare ammonia behavior in water vs methylbenzene
-Explain formation of ammonium hydroxide
-Write equations for ammonia dissolution in water

Class experiment: Test dry ammonia with dry litmus. Dissolve ammonia in water and test with litmus. Dissolve ammonia in methylbenzene and test with litmus. Record observations in table. Write equation for NH₃ + H₂O reaction. Explain why only aqueous ammonia shows basic properties.

Dry ammonia gas, distilled water, methylbenzene, red litmus paper, test tubes, gas collection apparatus

KLB Secondary Chemistry Form 4, Pages 9-10