ACIDS, BASES AND SALTS

Definition of Acids

By the end of the lesson, the learner should be able to:
- Define an acid in terms of hydrogen ions
-Investigate reactions of magnesium and zinc carbonate with different acids
-Write equations for reactions taking place
-Explain why magnesium strip should be cleaned

Class experiment: React cleaned magnesium strips with 2M HCl, 2M ethanoic acid, 2M H₂SO₄, 2M ethanedioic acid. Record observations in table. Repeat using zinc carbonate. Write chemical equations. Discuss hydrogen ion displacement and gas evolution.

Magnesium strips, zinc carbonate, 2M HCl, 2M ethanoic acid, 2M H₂SO₄, 2M ethanedioic acid, test tubes, test tube rack

KLB Secondary Chemistry Form 4, Pages 1-3

ACIDS, BASES AND SALTS

Strength of Acids
Definition of Bases
Strength of Bases

By the end of the lesson, the learner should be able to:
- Compare strengths of acids using pH values
-Determine strengths of acids by comparing their electrical conductivity
-Classify acids as either strong or weak
-Explain complete and partial dissociation of acids

Class experiment: Test pH of 2M HCl and 2M ethanoic acid using universal indicator. Set up electrical conductivity apparatus with both acids. Record milliammeter readings. Compare results and explain in terms of hydrogen ion concentration. Discuss strong vs weak acid definitions.

2M HCl, 2M ethanoic acid, universal indicator, pH chart, electrical conductivity apparatus, milliammeter, carbon electrodes, beakers, wires
Calcium hydroxide, red litmus paper, phenolphthalein indicator, distilled water, test tubes, spatula, evaporating dish
2M NaOH, 2M ammonia solution, universal indicator, pH chart, electrical conductivity apparatus, milliammeter, carbon electrodes

KLB Secondary Chemistry Form 4, Pages 3-5

ACIDS, BASES AND SALTS

Acid-Base Reactions
Effect of Solvent on Acids
Effect of Solvent on Bases

By the end of the lesson, the learner should be able to:
- Write equations for acid-base reactions
-Explain neutralization process
-Identify products of acid-base reactions
-Demonstrate formation of salt and water

Q/A: Review acid and base definitions. Demonstrate neutralization reactions: HCl + NaOH, H₂SO₄ + Ca(OH)₂, HNO₃ + KOH. Write molecular and ionic equations. Explain H⁺ + OH⁻ → H₂O. Discuss salt formation. Use indicators to show neutralization point.

Various acids and bases from previous lessons, indicators, beakers, measuring cylinders, stirring rods
HCl gas, distilled water, methylbenzene, magnesium ribbon, calcium carbonate, litmus paper, test tubes, gas absorption apparatus
Dry ammonia gas, distilled water, methylbenzene, red litmus paper, test tubes, gas collection apparatus

KLB Secondary Chemistry Form 4, Pages 6-7

ACIDS, BASES AND SALTS

Amphoteric Oxides and Hydroxides
Definition of Salts and Precipitation
Solubility of Chlorides, Sulphates and Sulphites
Complex Ions Formation

By the end of the lesson, the learner should be able to:
- Define amphoteric oxides
-Identify some amphoteric oxides
-Investigate reactions with both acids and alkalis
-Write equations for amphoteric behavior
- Explain formation of complex ions
-Investigate reactions with excess sodium hydroxide and ammonia
-Identify metal ions that form complex ions
-Write equations for complex ion formation

Class experiment: React Al₂O₃, ZnO, PbO, Zn(OH)₂, Al(OH)₃, Pb(OH)₂ with 2M HNO₃ and 2M NaOH. Warm mixtures. Record observations in table. Write equations showing basic and acidic behavior. Discuss dual nature of amphoteric substances.
Class experiment: Add NaOH dropwise then in excess to Mg²⁺, Ca²⁺, Zn²⁺, Al³⁺, Cu²⁺, Fe²⁺, Fe³⁺, Pb²⁺ solutions. Repeat with NH₃ solution. Record observations showing precipitate formation and dissolution. Write equations for complex ion formation: [Zn(OH)₄]²⁻, [Al(OH)₄]⁻, [Pb(OH)₄]²⁻, [Zn(NH₃)₄]²⁺, [Cu(NH₃)₄]²⁺.

Al₂O₃, ZnO, PbO, Zn(OH)₂, Al(OH)₃, Pb(OH)₂, 2M HNO₃, 2M NaOH, boiling tubes, heating source
Na₂CO₃ solution, salt solutions containing various metal ions, test tubes, droppers
2M NaCl, 2M Na₂SO₄, 2M Na₂SO₃, 0.1M salt solutions, dilute HCl, test tubes, heating source
2M NaOH, 2M NH₃ solution, 0.5M salt solutions, test tubes, droppers

KLB Secondary Chemistry Form 4, Pages 10-11
KLB Secondary Chemistry Form 4, Pages 15-16

ACIDS, BASES AND SALTS

Solubility and Saturated Solutions
Effect of Temperature on Solubility

By the end of the lesson, the learner should be able to:
- Define the term solubility
-Determine solubility of a given salt at room temperature
-Calculate mass of solute and solvent
-Express solubility in different units

Class experiment: Weigh evaporating dish and watch glass. Measure 20cm³ saturated KNO₃ solution. Record temperature. Evaporate to dryness carefully. Calculate masses of solute, solvent, and solution. Determine solubility per 100g water and in moles per litre. Discuss definition and significance.

Saturated KNO₃ solution, evaporating dish, watch glass, measuring cylinder, thermometer, balance, heating source
KClO₃, measuring cylinders, thermometer, burette, boiling tubes, heating source, graph paper

KLB Secondary Chemistry Form 4, Pages 16-18

ACIDS, BASES AND SALTS

Solubility Curves and Applications

By the end of the lesson, the learner should be able to:
- Plot solubility curves for various salts
-Use solubility curves to determine mass of crystals formed
-Apply solubility curves to practical problems
-Compare solubility patterns of different salts

Using data from textbook, plot solubility curves for KNO₃, KClO₃, NaCl, CaSO₄. Calculate mass of crystals deposited when saturated solutions are cooled. Work through examples: KClO₃ cooled from 70°C to 30°C. Discuss applications in salt extraction and purification.

Graph paper, ruler, pencil, calculator, data tables from textbook

KLB Secondary Chemistry Form 4, Pages 20-21

ACIDS, BASES AND SALTS

Fractional Crystallization
Hardness of Water - Investigation

By the end of the lesson, the learner should be able to:
- Define fractional crystallization
-Apply knowledge of solubility curves in separation of salts
-Calculate masses of salts that crystallize
-Explain separation of salt mixtures

Work through separation problems using solubility data for KNO₃ and KClO₃ mixtures. Calculate which salt crystallizes first when cooled from 50°C to 20°C. Plot combined solubility curves. Discuss applications in Lake Magadi and Ngomeni salt works. Solve practice problems.

Calculator, graph paper, data tables, worked examples from textbook
Soap solution, burette, various salt solutions, conical flasks, distilled water, tap water, rainwater, heating source

KLB Secondary Chemistry Form 4, Pages 21-22

ACIDS, BASES AND SALTS

Types and Causes of Water Hardness
Effects of Hard Water
Methods of Removing Hardness I

By the end of the lesson, the learner should be able to:
- Define temporary and permanent hardness
-Explain causes of temporary hardness
-Explain causes of permanent hardness
-Write equations for decomposition of hydrogen carbonates
- State disadvantages of hard water
-State advantages of hard water
-Explain formation of scum and fur
-Discuss economic and health implications

Q/A: Review previous experiment results. Explain temporary hardness caused by Ca(HCO₃)₂ and Mg(HCO₃)₂. Write decomposition equations when boiled. Explain permanent hardness caused by CaSO₄, MgSO₄, Ca(NO₃)₂, Mg(NO₃)₂. Discuss why permanent hardness cannot be removed by boiling.
Discussion based on practical experience: Soap wastage, scum formation on clothes, fur in kettles and pipes, pipe bursting in boilers. Advantages: calcium for bones, protection of lead pipes, use in brewing. Show examples of fur deposits. Calculate economic costs of hard water in households.

Student books, examples from previous experiment, chalkboard for equations
Samples of fur deposits, pictures of scaled pipes, calculator for cost analysis
Hard water samples, heating source, soap solution, distillation apparatus diagram

KLB Secondary Chemistry Form 4, Pages 24-25

ACIDS, BASES AND SALTS
ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Methods of Removing Hardness II
Endothermic and Exothermic Reactions

By the end of the lesson, the learner should be able to:
- Explain removal using sodium carbonate
-Describe ion exchange method
-Explain removal using calcium hydroxide and ammonia
-Write equations for all processes

Demonstrate addition of Na₂CO₃ to hard water - observe precipitation. Explain ion exchange using resin (NaX) showing Ca²⁺ + 2NaX → CaX₂ + 2Na⁺. Discuss regeneration with brine. Write equations for Ca(OH)₂ and NH₃ methods. Compare all methods for effectiveness and cost.

Na₂CO₃ solution, hard water samples, ion exchange resin diagram, Ca(OH)₂, NH₃ solution
250ml plastic beakers, tissue paper, rubber bands, NH₄NO₃, NaOH pellets, distilled water, thermometers, spatulas, measuring cylinders

KLB Secondary Chemistry Form 4, Pages 25-26

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Enthalpy Notation and Energy Content

By the end of the lesson, the learner should be able to:
- Define enthalpy and enthalpy change
-Use the symbol ΔH to represent enthalpy changes
-Calculate enthalpy changes using the formula ΔH = H(products) - H(reactants)
-Distinguish between positive and negative enthalpy changes

Q/A: Review previous experiment results. Introduce enthalpy symbol H and enthalpy change ΔH. Calculate enthalpy changes from previous experiments. Explain why endothermic reactions have positive ΔH and exothermic reactions have negative ΔH. Practice calculations with worked examples.

Student books, calculators, worked examples from textbook, chalkboard for calculations

KLB Secondary Chemistry Form 4, Pages 31-32

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Bond Breaking and Bond Formation
Latent Heat of Fusion and Vaporization

By the end of the lesson, the learner should be able to:
- Explain that energy changes are due to bond breaking and bond formation
-Describe bond breaking as endothermic and bond formation as exothermic
-Investigate energy changes during melting and boiling
-Plot heating curves for pure substances

Class experiment: Heat crushed ice while stirring with thermometer. Record temperature every minute until ice melts completely, then continue until water boils. Plot temperature-time graph. Explain constant temperature during melting and boiling in terms of bond breaking. Discuss latent heat of fusion and vaporization.

Crushed pure ice, 250ml glass beakers, thermometers, heating source, stopwatch, graph paper, stirring rods
Data tables showing molar heats of fusion/vaporization, calculators, heating curves from previous lesson

KLB Secondary Chemistry Form 4, Pages 32-35

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Bond Energy Calculations
Determination of Enthalpy of Solution I
Thermochemical Equations

By the end of the lesson, the learner should be able to:
- Calculate energy changes in reactions using bond energies
-Apply the formula: Heat of reaction = Bond breaking energy + Bond formation energy
-Determine whether reactions are exothermic or endothermic
-Use bond energy data to solve problems
- Determine the enthalpy changes of solution of ammonium nitrate and sodium hydroxide
-Calculate enthalpy change using ΔH = mcΔT
-Calculate number of moles of solute dissolved
-Determine molar heat of solution

Work through formation of HCl from H₂ and Cl₂ using bond energies. Calculate energy required to break H-H and Cl-Cl bonds. Calculate energy released when H-Cl bonds form. Apply formula: ΔH = Energy absorbed - Energy released. Practice with additional examples. Discuss why calculated values may differ from experimental values.
Class experiment: Dissolve exactly 2.0g NH₄NO₃ in 100ml distilled water in plastic beaker. Record temperature change. Repeat with 2.0g NaOH. Calculate enthalpy changes using ΔH = mcΔT where m = 100g, c = 4.2 kJ kg⁻¹K⁻¹. Calculate moles dissolved and molar heat of solution.

Bond energy data tables, calculators, worked examples, practice problems
250ml plastic beakers, 2.0g samples of NH₄NO₃ and NaOH, distilled water, thermometers, measuring cylinders, analytical balance, calculators
Results from previous experiment, graph paper for energy level diagrams, practice examples

KLB Secondary Chemistry Form 4, Pages 35-36
KLB Secondary Chemistry Form 4, Pages 36-38

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Enthalpy of Solution of Concentrated Sulphuric Acid

By the end of the lesson, the learner should be able to:
- Determine heat of solution of concentrated sulphuric(VI) acid
-Apply safety precautions when handling concentrated acids
-Calculate enthalpy change considering density and purity
-Write thermochemical equation for the reaction

Teacher demonstration: Carefully add 2cm³ concentrated H₂SO₄ to 98cm³ distilled water in wrapped beaker (NEVER vice versa). Record temperature change. Calculate mass of acid using density (1.84 g/cm³) and purity (98%). Calculate molar heat of solution. Emphasize safety - always add acid to water.

Concentrated H₂SO₄, distilled water, 250ml plastic beaker, tissue paper, measuring cylinders, thermometer, safety equipment

KLB Secondary Chemistry Form 4, Pages 39-41

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Enthalpy of Combustion
Enthalpy of Displacement

By the end of the lesson, the learner should be able to:
- Define molar heat of combustion
-Determine enthalpy of combustion of ethanol experimentally
-Explain why experimental values differ from theoretical values
-Calculate molar enthalpy of combustion from experimental data

Class experiment: Burn ethanol in small bottle with wick to heat 100cm³ water in glass beaker. Record initial and final masses of bottle+ethanol and temperature change. Calculate moles of ethanol burned and heat evolved. Determine molar enthalpy of combustion. Compare with theoretical value (-1368 kJ/mol). Discuss sources of error.

Ethanol, small bottles with wicks, 250ml glass beakers, tripod stands, wire gauze, thermometers, analytical balance, measuring cylinders
Zinc powder, 0.5M CuSO₄ solution, 250ml plastic beakers, tissue paper, thermometers, analytical balance, stirring rods

KLB Secondary Chemistry Form 4, Pages 41-44

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Enthalpy of Neutralization
Standard Conditions and Standard Enthalpy Changes

By the end of the lesson, the learner should be able to:
- Define molar heat of neutralization
-Determine heat of neutralization of HCl with NaOH
-Compare neutralization enthalpies of strong and weak acids/bases
-Write ionic equations for neutralization reactions

Class experiment: Mix 50cm³ of 2M HCl with 50cm³ of 2M NaOH in wrapped beaker. Record temperature changes. Calculate molar heat of neutralization. Repeat with weak acid (ethanoic) and weak base (ammonia). Compare values. Write ionic equations. Explain why strong acid + strong base gives ~57.2 kJ/mol.

2M HCl, 2M NaOH, 2M ethanoic acid, 2M ammonia solution, measuring cylinders, thermometers, 250ml plastic beakers, tissue paper
Student books, examples of standard enthalpy data, notation practice exercises

KLB Secondary Chemistry Form 4, Pages 47-49

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Hess's Law - Introduction and Theory
Energy Cycle Diagrams
Hess's Law Calculations

By the end of the lesson, the learner should be able to:
- State Hess's Law
-Explain the principle of energy conservation in chemical reactions
-Understand that enthalpy change is independent of reaction route
-Apply Hess's Law to simple examples
- Draw energy cycle diagrams
-Link enthalpy of formation with enthalpy of combustion
-Calculate unknown enthalpy changes using energy cycles
-Apply Hess's Law to determine enthalpy of formation

Introduce Hess's Law: "The energy change in converting reactants to products is the same regardless of the route by which the chemical change occurs." Use methane formation example to show two routes giving same overall energy change. Draw energy cycle diagrams. Explain law of conservation of energy application.
Work through energy cycle for formation of CO from carbon and oxygen using combustion data. Draw cycle showing Route 1 (direct combustion) and Route 2 (formation then combustion). Calculate ΔH°f(CO) = ΔH°c(C) - ΔH°c(CO). Practice with additional examples including ethanol formation.

Energy cycle diagrams for methane formation, chalkboard illustrations, worked examples from textbook
Graph paper, energy cycle templates, combustion data tables, calculators
Worked examples, combustion data, calculators, step-by-step calculation sheets

KLB Secondary Chemistry Form 4, Pages 49-52
KLB Secondary Chemistry Form 4, Pages 52-54

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Lattice Energy and Hydration Energy

By the end of the lesson, the learner should be able to:
- Define lattice energy and hydration energy
-Explain relationship between heat of solution, lattice energy and hydration energy
-Draw energy cycles for dissolution of ionic compounds
-Calculate heat of solution using Born-Haber type cycles

Explain dissolution of NaCl: first lattice breaks (endothermic), then ions hydrate (exothermic). Define lattice energy as energy to form ionic solid from gaseous ions. Define hydration energy as energy when gaseous ions become hydrated. Draw energy cycle: ΔH(solution) = ΔH(lattice) + ΔH(hydration). Calculate for NaCl.

Energy cycle diagrams, lattice energy and hydration energy data tables, calculators

KLB Secondary Chemistry Form 4, Pages 54-56

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Factors Affecting Lattice and Hydration Energies
Definition and Types of Fuels

By the end of the lesson, the learner should be able to:
- Explain factors affecting lattice energy
-Explain factors affecting hydration energy
-Use data tables to identify trends
-Calculate enthalpies of solution for various ionic compounds

Analyze data tables showing lattice energies (Table 2.7) and hydration energies (Table 2.6). Identify trends: smaller ions and higher charges give larger lattice energies and hydration energies. Calculate heat of solution for MgCl₂ using: ΔH(solution) = +2489 + (-1891 + 2×(-384)) = -170 kJ/mol. Practice with other compounds.

Data tables from textbook, calculators, trend analysis exercises
Examples of different fuels, classification charts, pictures of fuel types

KLB Secondary Chemistry Form 4, Pages 54-56

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Heating Values of Fuels

By the end of the lesson, the learner should be able to:
- Define heating value of a fuel
-Calculate heating values from molar enthalpies of combustion
-Compare heating values of different fuels
-Explain units of heating value (kJ/g)

Calculate heating value of ethanol: ΔH°c = -1360 kJ/mol, Molar mass = 46 g/mol, Heating value = 1360/46 = 30 kJ/g. Compare heating values from Table 2.8: methane (55 kJ/g), fuel oil (45 kJ/g), charcoal (33 kJ/g), wood (17 kJ/g). Discuss significance of these values for fuel selection.

Heating value data table, calculators, fuel comparison charts

KLB Secondary Chemistry Form 4, Pages 56-57

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Factors in Fuel Selection
Environmental Effects of Fuels
Fuel Safety and Precautions
Endothermic and Exothermic Reactions

By the end of the lesson, the learner should be able to:
- State factors that influence choice of fuel
-Explain why different fuels are chosen for different purposes
-Compare advantages and disadvantages of various fuels
-Apply selection criteria to real situations
- State precautions necessary when using fuels
-Explain safety measures for different fuel types
-Identify hazards associated with improper fuel handling
-Apply safety principles to local situations

Discuss seven factors: heating value, ease of combustion, availability, transportation, storage, environmental effects, cost. Compare wood/charcoal for domestic use vs methylhydrazine for rockets. Analyze why each is suitable for its purpose. Students suggest best fuels for cooking, heating, transport in their area.
Discuss safety precautions: ventilation for charcoal stoves (CO poisoning), not running engines in closed garages, proper gas cylinder storage, fuel storage away from populated areas, keeping away from fuel spills. Relate to local situations and accidents. Students identify potential hazards in their environment.

Fuel comparison tables, local fuel availability data, cost analysis sheets
Pictures of environmental damage, pollution data, examples of clean technology
Safety guideline charts, examples of fuel accidents, local safety case studies
250ml plastic beakers, tissue paper, NH₄NO₃, NaOH pellets, distilled water, thermometers, calculators

KLB Secondary Chemistry Form 4, Pages 57
KLB Secondary Chemistry Form 4, Pages 57-58

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES

Bond Breaking, Formation and Phase Changes

By the end of the lesson, the learner should be able to:
- Explain that energy changes are due to bond breaking and bond formation
-Investigate energy changes when solids and liquids are heated
-Define latent heat of fusion and vaporization
-Calculate energy changes using bond energies

Class experiment: Heat ice to melting then boiling, record temperature every minute. Plot heating curve. Explain constant temperature periods. Define latent heat of fusion/vaporization. Calculate energy changes in H₂ + Cl₂ → 2HCl using bond energies. Apply formula: ΔH = Energy absorbed - Energy released.

Ice, glass beakers, thermometers, heating source, graph paper, bond energy data tables

KLB Secondary Chemistry Form 4, Pages 32-36

ENERGY CHANGES IN PHYSICAL AND CHEMICAL PROCESSES
REACTION RATES AND REVERSIBLE REACTIONS

Determination of Enthalpy of Solution
Definition of Reaction Rate and Collision Theory

By the end of the lesson, the learner should be able to:
- Carry out experiments to determine enthalpy changes of solution
-Calculate enthalpy change using ΔH = mcΔT
-Write correct thermochemical equations
-Define molar heat of solution

Class experiment: Dissolve exactly 2.0g NH₄NO₃ and 2.0g NaOH separately in 100ml water. Record temperature changes. Calculate enthalpy changes using ΔH = mcΔT. Calculate moles and molar heat of solution. Write thermochemical equations: NH₄NO₃(s) + aq → NH₄NO₃(aq) ΔH = +25.2 kJ mol⁻¹.

2.0g samples of NH₄NO₃ and NaOH, plastic beakers, thermometers, analytical balance, calculators
Examples of fast/slow reactions, energy diagram templates, chalk/markers for diagrams

KLB Secondary Chemistry Form 4, Pages 36-39

REACTION RATES AND REVERSIBLE REACTIONS

Effect of Concentration on Reaction Rate

By the end of the lesson, the learner should be able to:
- Explain the effect of concentration on reaction rates
-Investigate reaction of magnesium with different concentrations of sulphuric acid
-Illustrate reaction rates graphically and interpret experimental data
-Calculate concentrations and plot graphs of concentration vs time

Class experiment: Label 4 conical flasks A-D. Add 40cm³ of 2M H₂SO₄ to A, dilute others with water (30+10, 20+20, 10+30 cm³). Drop 2cm magnesium ribbon into each, time complete dissolution. Record in Table 3.1. Calculate concentrations, plot graph. Explain: higher concentration → more collisions → faster reaction.

4 conical flasks, 2M H₂SO₄, distilled water, magnesium ribbon, stopwatch, measuring cylinders, graph paper

KLB Secondary Chemistry Form 4, Pages 65-67

REACTION RATES AND REVERSIBLE REACTIONS

Change of Reaction Rate with Time
Effect of Temperature on Reaction Rate
Effect of Surface Area on Reaction Rate

By the end of the lesson, the learner should be able to:
- Describe methods used to measure rate of reaction
-Investigate how reaction rate changes as reaction proceeds
-Plot graphs of volume of gas vs time
-Calculate average rates at different time intervals
- Explain the effect of surface area on reaction rates
-Investigate reaction of marble chips vs marble powder with HCl
-Compare reaction rates using gas collection
-Relate particle size to surface area and collision frequency

Class experiment: React 2cm magnesium ribbon with 100cm³ of 0.5M HCl in conical flask. Collect H₂ gas in graduated syringe as in Fig 3.4. Record gas volume every 30 seconds for 5 minutes in Table 3.2. Plot volume vs time graph. Calculate average rates between time intervals. Explain why rate decreases as reactants are consumed.
Class experiment: React 2.5g marble chips with 50cm³ of 1M HCl, collect CO₂ gas using apparatus in Fig 3.10. Record gas volume every 30 seconds. Repeat with 2.5g marble powder. Record in Table 3.5. Plot both curves on same graph. Write equation: CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂. Explain: smaller particles → larger surface area → more collision sites → faster reaction.

0.5M HCl, magnesium ribbon, conical flask, gas collection apparatus, graduated syringe, stopwatch, graph paper
0.15M Na₂S₂O₃, 2M HCl, conical flasks, water baths at different temperatures, paper with cross marked, stopwatch, thermometers
Marble chips, marble powder, 1M HCl, gas collection apparatus, balance, conical flasks, measuring cylinders, graph paper

KLB Secondary Chemistry Form 4, Pages 67-70
KLB Secondary Chemistry Form 4, Pages 73-76

REACTION RATES AND REVERSIBLE REACTIONS

Effect of Catalysts on Reaction Rate
Effect of Light and Pressure on Reaction Rate

By the end of the lesson, the learner should be able to:
- Explain effects of suitable catalysts on reaction rates
-Investigate decomposition of hydrogen peroxide with and without catalyst
-Define catalyst and explain how catalysts work
-Compare activation energies in catalyzed vs uncatalyzed reactions

Class experiment: Decompose 5cm³ of 20-volume H₂O₂ in 45cm³ water without catalyst, collect O₂ gas. Repeat adding 2g MnO₂ powder. Record gas volumes as in Fig 3.12. Compare rates and final mass of MnO₂. Write equation: 2H₂O₂ → 2H₂O + O₂. Define catalyst and explain how it lowers activation energy. Show energy diagrams for both pathways.

20-volume H₂O₂, MnO₂ powder, gas collection apparatus, balance, conical flasks, filter paper, measuring cylinders
0.1M KBr, 0.05M AgNO₃, test tubes, dark cupboard, direct light source, examples of photochemical reactions

KLB Secondary Chemistry Form 4, Pages 76-78

REACTION RATES AND REVERSIBLE REACTIONS

Reversible Reactions
Chemical Equilibrium

By the end of the lesson, the learner should be able to:
- State examples of simple reversible reactions
-Investigate heating of hydrated copper(II) sulphate
-Write equations for reversible reactions using double arrows
-Distinguish between reversible and irreversible reactions

Class experiment: Heat CuSO₄·5H₂O crystals in boiling tube A, collect liquid in tube B as in Fig 3.15. Observe color changes: blue → white + colorless liquid. Pour liquid back into tube A, observe return to blue. Write equation with double arrows: CuSO₄·5H₂O ⇌ CuSO₄ + 5H₂O. Give other examples: NH₄Cl ⇌ NH₃ + HCl. Compare with irreversible reactions.

CuSO₄·5H₂O crystals, boiling tubes, delivery tube, heating source, test tube holder
0.5M NaOH, 0.5M HCl, universal indicator, boiling tubes, droppers, examples of equilibrium systems

KLB Secondary Chemistry Form 4, Pages 78-80

REACTION RATES AND REVERSIBLE REACTIONS

Le Chatelier's Principle and Effect of Concentration

By the end of the lesson, the learner should be able to:
- State Le Chatelier's Principle
-Explain effect of concentration changes on equilibrium position
-Investigate bromine water equilibrium with acid/base addition
-Apply Le Chatelier's Principle to predict equilibrium shifts

Experiment: Add 2M NaOH dropwise to 20cm³ bromine water until colorless. Then add 2M HCl until excess, observe color return. Write equation: Br₂ + H₂O ⇌ HBr + HBrO. Explain Le Chatelier's Principle: "When change applied to system at equilibrium, system moves to oppose that change." Demonstrate with chromate/dichromate equilibrium: CrO₄²⁻ + H⁺ ⇌ Cr₂O₇²⁻ + H₂O.

Bromine water, 2M NaOH, 2M HCl, beakers, chromate/dichromate solutions for demonstration

KLB Secondary Chemistry Form 4, Pages 82-84

REACTION RATES AND REVERSIBLE REACTIONS
REACTION RATES AND REVERSIBLE REACTIONS
RADIOACTIVITY

Effect of Pressure and Temperature on Equilibrium
Industrial Applications - Haber Process
Industrial Applications - Contact Process
Introduction, Nuclear Stability and Types of Radioactivity

By the end of the lesson, the learner should be able to:
- Explain effect of pressure changes on equilibrium
-Explain effect of temperature changes on equilibrium
-Investigate NO₂/N₂O₄ equilibrium with temperature
-Apply Le Chatelier's Principle to industrial processes
- Apply equilibrium principles to Contact Process
-Explain optimum conditions for sulphuric acid manufacture
-Compare different industrial equilibrium processes
-Evaluate economic factors in industrial chemistry

Teacher demonstration: React copper turnings with concentrated HNO₃ to produce NO₂ gas in test tube. Heat and cool the tube, observe color changes: brown ⇌ pale yellow representing 2NO₂ ⇌ N₂O₄. Explain pressure effects using molecule count. Show Table 3.7 with pressure effects. Discuss temperature effects: heating favors endothermic direction, cooling favors exothermic direction. Use Table 3.8.
Analyze Contact Process: 2SO₂ + O₂ ⇌ 2SO₃ ΔH = -197 kJ/mol. Apply principles: high pressure favors forward reaction (3 molecules → 2 molecules), low temperature favors exothermic reaction. Explain optimum conditions: 450°C, atmospheric pressure, V₂O₅ catalyst, 96% conversion. Compare with Haber Process. Discuss catalyst choice and economic factors.

Copper turnings, concentrated HNO₃, test tubes, heating source, ice bath, gas collection apparatus, safety equipment
Haber Process flow diagram, equilibrium data showing temperature/pressure effects on NH₃ yield, industrial catalyst information
Contact Process flow diagram, comparison table with Haber Process, catalyst effectiveness data
Periodic table, atomic structure charts, Table 7.1, nuclear stability diagrams

KLB Secondary Chemistry Form 4, Pages 84-87
KLB Secondary Chemistry Form 4, Pages 89

RADIOACTIVITY

Types of Radiation and Their Properties
Radioactive Decay and Half-Life Concept
Half-Life Calculations and Problem Solving

By the end of the lesson, the learner should be able to:
Identify alpha, beta, and gamma radiations
- Compare penetrating abilities and ionizing power
- Explain electric field deflection
- Analyze safety implications

Study alpha (α), beta (β), gamma (γ) characteristics
- Figure 7.2 - penetrating power demonstration
- Figure 7.3 - electric field effects
- Discussion on radiation protection and detection

Radiation type charts, penetration diagrams, electric field illustrations, safety equipment charts
Graph paper, Table 7.2 data, calculators, decay curve examples, half-life data table
Calculators, comprehensive problem sets, worked examples, isotope half-life comparison tables

KLB Secondary Chemistry Form 4, Pages 201-204

RADIOACTIVITY

Nuclear Reactions and Equations
Radioactive Decay Series and Sequential Reactions
Nuclear Fission and Chain Reactions

By the end of the lesson, the learner should be able to:
Write balanced nuclear equations
- Apply conservation laws for mass and atomic numbers
- Explain alpha and beta emission effects
- Balance complex nuclear reactions

Practice writing nuclear equations for alpha emission
- Study beta emission examples
- Apply mass and atomic number conservation
- Balance various nuclear reactions with missing nuclides

Nuclear equation examples, periodic table, conservation law charts, practice worksheets
Decay series charts, thorium series diagram, nuclide stability charts, practice decay series
Fission reaction diagrams, chain reaction illustrations, nuclear reactor diagrams, energy calculation examples

KLB Secondary Chemistry Form 4, Pages 205-207

RADIOACTIVITY

Nuclear Fusion and Energy Comparisons
Medical and Diagnostic Applications
Industrial, Agricultural and Dating Applications

By the end of the lesson, the learner should be able to:
Define nuclear fusion process
- Compare fusion with fission processes
- Write fusion equations
- Explain stellar energy production and fusion applications

Study hydrogen fusion examples
- Compare fusion vs fission characteristics and energy yields
- Stellar fusion processes
- Hydrogen bomb vs nuclear reactor principles

Fusion reaction diagrams, comparison tables, stellar fusion charts, energy comparison data
Medical radioisotope charts, treatment procedure diagrams, diagnostic equipment images, case studies
Carbon dating examples, agricultural application charts, industrial use diagrams, food preservation data

KLB Secondary Chemistry Form 4, Pages 207-208

RADIOACTIVITY

Radiation Hazards and Environmental Impact
Safety Measures and International Control
Half-Life Problem Solving and Graph Analysis
Nuclear Equations and Conservation Laws

By the end of the lesson, the learner should be able to:
Identify radiation health hazards
- Explain genetic mutation effects
- Discuss major nuclear accidents
- Analyze long-term environmental contamination
Explain radiation protection principles
- Describe proper storage and disposal methods
- Discuss IAEA role and standards
- Analyze monitoring and control systems

Study Chernobyl and Three Mile Island accidents
- Genetic mutation and cancer effects
- Long-term radiation exposure consequences
- Nuclear waste disposal challenges
Study IAEA guidelines and international cooperation
- Radiation protection protocols and ALARA principle
- Safe storage, transport and disposal methods
- Environmental monitoring systems

Accident case studies, environmental impact data, radiation exposure charts, contamination maps
IAEA guidelines, safety protocol charts, monitoring equipment diagrams, international cooperation data
Graph paper, experimental data sets, calculators, statistical analysis examples, comprehensive problem sets
Nuclear equation worksheets, periodic table, decay series diagrams, conservation law examples

KLB Secondary Chemistry Form 4, Pages 209-210